Detalhes do Documento

Liquid-liquid equilibrium phase diagrams of new aqueous two-phase systems : Uco...

Autor(es): Pereira, Martinha cv logo 1 ; You-Ting Wu cv logo 2 ; Madeira, Pedro cv logo 3 ; Venâncio, Armando cv logo 4 ; Macedo, Eugénia cv logo 5 ; Teixeira, J. A. cv logo 6

Data: 2004

Identificador Persistente: http://hdl.handle.net/1822/1486

Origem: RepositóriUM - Universidade do Minho


Descrição
The phase diagrams of Ucon 50-HB-5100 (Ucon) + ammonium sulfate (NH4)2SO4 + water, Ucon 50-HB- 5100 + poly(vinyl alcohol) 10000 (PVA 10000) + water, Ucon 50-HB-5100 + hydroxypropyl starch (Reppal PES 100) + water, and poly(ethylene glycol) 8000 (PEG 8000)-PVA 10000 systems were determined at 22 °C. Measurements at 30 and 40 °C were also done for each Ucon-salt system. A linear regression was used to calculate the slope and standard deviation for each tie line. The standard deviations are in most situations lower than 0.1, and the tie-line slopes for each phase diagram vary within 5.5% around the medium value for all cases with the exception of the Ucon + (NH4)2SO4 + water system at 40 °C. The phase diagrams of the Ucon + (NH4)2SO4 + water system at different temperatures were shown to have a smaller amount of salt and polymer than conventional systems and to be thermoseparating, versatile, and particularly attractive, since phase formation is temperature-dependent. The phase diagrams of Ucon + PVA 10000 + water, Ucon + PES + water, and PEG + PVA 10000 + water systems were very similar, since high polymer concentrations (PES or PVA 10000) are required to form the two phases.
Tipo de Documento Artigo
Idioma Inglês
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