Author(s):
Vilas-Boas, Miguel 
; Freire, C. ; Castro, B. ; Christensen, P.A. ; Hillman, A.R.
Date: 1997
Persistent ID: http://hdl.handle.net/10198/5892
Origin: Biblioteca Digital do IPB
Document details
New Insigths into the structure and properties of electroactive polymer filmes ...
Description
Oxidative electrochemical polymerization of (N,N'-ethylenebis(salicylideneaminato)) nickel(II), [Ni(salen)], in acetonitrile/TEAP was reinvestigated. The polymers were characterized by in situ FTIR and UV-visible spectroscopies in order to explore film structure and to clarify the electronic states as a function of the electrochemically controlled applied redox potential; oxidized species involved in polymerization and oxidative switching of the polymer were also assessed by ex situ EPR experiments.
Oxidative electrochemical polymerization of (N,N'-ethylenebis(salicylideneaminato)) nickel(II), [Ni(salen)], in acetonitrile/TEAP was reinvestigated. The polymers were characterized by in situ FTIR and UV-visible spectroscopies in order to explore film structure and to clarify the electronic states as a function of the electrochemically controlled applied redox potential; oxidized species involved in polymerization and oxidative switching of the polymer were also assessed by ex situ EPR experiments.
Document Type
Article
Language English
Language English
| Financiadores do RCAAP | |||||||
|
|
|
|
|
|
||