Ethyl 2-(Diisopropoxyphosphoryl)-2H-azirine-3-carboxylate: reactions with Nucle...

• Autor(es): Lemos, A. ; Alves, Maria José Chão
• Data: 2009
• Identificador Persistente: http://hdl.handle.net/10400.1/1042
• Origem: Sapientia - Universidade do Algarve
• Assunto(s): Azirinas; Cicloadição; Diels-Alder; Heterociclos; Aminoacidos
• Tipo de Documento: Artigo
• Idioma: Inglês

Descrição

Ethyl 2-(diisopropoxyphosphoryl)-2H-azirine-3-carboxylate, the first example of an azirine bearing simultaneously ester and phosphonate groups was generated in situ and reacted with a number of 1,3-dienes. Cycloadducts or their ensuing rearranged products were isolated in moderate yields.