Descrição
Ti–Si–Al–N films were prepared by rf reactive magnetron sputtering, in static and rotation modes, using
a wide range of different deposition conditions, which created conditions to obtain Ti–Al–Si–N coatings
with different structural arrangements.
Films prepared below a critical nitrogen flow, under conditions out of thermodynamic equilibrium,
revealed a preferential growth of an fcc (Ti,Al,Si)Nx compound with a small N deficiency. With nitrogen
flow above that critical value, the reduction of the lattice parameter was no longer detected. However,
a thermal annealing showed that a complete thermodynamically driven segregation of the TiN and Si3N4
phases was not yet obtained. The segregation upon annealing induced a self-hardening and showed
a multiphase system, where the crystalline TiN, (Ti,Al)N and (Ti,Al,Si)Nx phases were identified by X-ray
diffraction. This behavior is due to the de-mixing of the solid solution associated to a small N deficiency.
; Rebouta, L. 
