Convenient Synthesis of 3-Vinyl and

• Autor(es): Gordo, Joana ; Avó, João ; Parola, Jorge ; Lima, João ; Pereira, António ; Branco, Paula
• Data: 2011
• Identificador Persistente: http://hdl.handle.net/10174/3465
• Origem: Repositório Científico da Universidade de Évora
• Assunto(s): 3-Vinyl Coumarins; 3-Styryl Coumarins
• Tipo de Documento: Artigo
• Idioma: Inglês

Descrição

A variety of 2-hydroxy aldehydes on reaction with 3-butenoic acid afford in a one-pot reaction the corresponding 3-vinylcoumarins. As expected, extension of the delocalized π-electron system accomplished by Heck coupling reactions with aryl halides results in an increased fluorescence of the compounds whose applicability is yet to be established.