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Synthesis of novel carboxylated benzoxazolylcoumarins

Rodrigues, Lígia M.; X. H. Luan; Oliveira, Ana M. A. G.; Campos, Ana M. F. Oliveira

Six novel coumarins containing carboxylic ester or acid groups were prepared. The compounds were characterised by the usual methods. In a few cases the fluorescence data were obtained.


Synthesis of fluorescent 3-benzoxazol-2-yl-coumarins

X. H. Luan; Cerqueira, N. M. F. S. A.; Oliveira, Ana M. A. G.; Raposo, M. Manuela M.; Rodrigues, Lígia M.; Coelho, Paulo J.; Campos, Ana M. F. Oliveira

Twelve 3-benzoxazol-2-yl-coumarins (1-3) were synthesised by reacting various ortho-aminophenols with three coumarin-3-carboxylic acids either directly or by formation of the intermediate amide. The cyclodehydrating agent was polyphosphoric acid (PPA). The compounds were characterised by spectroscopic methods. Absorption and fluorescence spectra of the compounds have also been recorded.


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Fundação para a Ciência e a Tecnologia Universidade do Minho   Governo Português Ministério da Educação e Ciência Programa Operacional da Sociedade do Conhecimento União Europeia