http://www.sciencedirect.com/science/article/B6TVH-4V2NP2J-14/2/e2844eb805cd79148fe2c51116014ae6
http://www.sciencedirect.com/science/article/B6TVH-4V2NP2J-1R/2/ae8c94d2ee3229b6fe7881d93d1a64eb
http://www.sciencedirect.com/science/article/B6TVH-4V2NP2J-20/2/625b6e64a430f4e722e4eec1de4d54ad
The diffusion dynamics of the neutral muonium state found in HgO is addressed in this work. We propose a hopping model for the diffusion, and use it to analyse time-domain [mu]SR data. It is found that the diffusion is an incoherent quantum process, with an activation energy of 5.2(2) meV. The analysis also points to the anti-bonding site as the best-suited candidate for the muon's localisation. ; http://www...
This work reports a spectroscopic and spin-dynamics [mu]SR study of the positive muon states formed in the phthalocyanines Zn-Pc, H2-Pc and Cu-Pc. In Zn-Pc and H2-Pc, three distinct muoniated radicals are formed, seen to undergo spin-dynamical processes with charge carriers. Two of the states have very similar hyperfine interaction values, and are believed to be due to muon addition at the outer benzene rings. ...
[mu]SR experiments were conducted on the organic semiconductor zinc-phthalocyanine (Zn-Pc) in order to identify and characterize the muon states in this material. Transverse-field experiments at 0.5 mT reveal the existence of paramagnetic muon states in Zn-Pc, with the formation probability of nearly 100%. Two different muoniated radicals were detected, with hyperfine parameters of 127 and 142 MHz; muonium is t...
The diffusion parameters of diamagnetic muons in chalcopyrites CuInSe2, CuInS2, CuInTe2, CuGaTe2 and (Ag0.25Cu0.75)InSe2 were obtained by [mu]SR methods. The variations among the different compositions were found to validate the anion-antibonding localization model. The application of a two-state model to the zero-field data revealed muon trapping by defects. The dipolar width at the trap and the number of jump...
Additional hydrogen in II-VI semiconductors may occur in two different configurations, either bound to the anion in a position along the bond direction, or at an open interstitial site surrounded by four cations. The electronic character of these states is very different: the bound hydrogen forms a donor with an extended electronic wave function, whereas the interstitial hydrogen is acceptor-like and has an alm...
The assignment of muon spin rotation spectra to muonium counterparts of hydrogen shallow-donor states is reviewed in four II-VI widegap semiconductors, CdS, CdSe, CdTe and ZnO. The existence of extended electronic orbitals is argued from the muon-electron hyperfine parameters and supported by the new muon spin repolarization data for CdS and ZnO, characterizing the superhyperfine parameters on the sparse Cd and...
A new type of muonium defect centre has been observed in undoped CdS at low temperatures (T<20Â K). The hyperfine parameters are A[short parallel]=335 (7)Â kHz and A[perpendicular]=199 (6)Â kHz (approximately 10-4 of the vacuum value) with the symmetry axis along the Cd-S bond direction. The disappearance of the centre at around 20Â K is in agreement with the binding energy of a shallow centre. The extremely we...
Financiadores do RCAAP | |||||||
![]() |
![]() |
![]() |
![]() |
![]() |
![]() |