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Surface hydrophobization of bacterial and vegetable cellulose fibers using ioni...
Tomé, Liliana C.; Freire, Mara G.; Rebelo, Luís Paulo N.; Silvestre, Armando J. D.; Carlos Pascoal Neto; Marrucho, Isabel M.; Freire, Carmen S. R.The surface hydrophobization through heterogeneous chemical modification of bacterial (and vegetable) cellulose fibers with several anhydrides (acetic, butyric, hexanoic and alkenyl succinic anhydrides) and hexanoyl chloride suspended in an ionic liquid, tetradecyltrihexylphosphonium bis(trifluoromethylsulfonyl) imide, [TDTHP][NTf(2)], was studied. Furthermore, in the reaction with hexanoyl chloride, another io...
Transparent bionanocomposites with improved properties prepared from acetylated...
Tomé, Liliana C.; Pinto, Ricardo J. B.; Trovatti, Eliane; Freire, Carmen S. R.; Silvestre, Armando J. D.; Neto, Carlos Pascoal; Gandini, AlessandroThe preparation and characterization of biocomposite materials with improved properties based on poly(lactic acid) (PLA) and bacterial cellulose, and, for comparative purposes, vegetal cellulose fibers, both in their pristine form or after acetylation, is reported. The composite materials were obtained through the simple and green mechanical compounding of a PLA matrix and bacterial cellulose nanofibrils (or ve...
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