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Excited-State Proton Transfer in Gas-Expanded Liquids: The Roles of Pressure a...
Nunes, Rui M. D.; Arnaut, Luís G.; Solntsev, Kyril M.; Tolbert, Laren M.; Formosinho, Sebastião J.Excited-state proton transfer from 5,8-dicyano-2-naphthol to methanol takes place in CO2/methanol mixtures, in the pressure and temperature ranges of supercritical CO2. The efficiency of the proton-transfer step decreases with the pressure. This is assigned to the perturbation of the methanol clusters solvating the naphthol. ; http://dx.doi.org/10.1021/ja052416o
Data: 2005
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Origem: Estudo Geral - Universidade de Coimbra
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