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Carbon formation on nickel and nickel-copper alloy catalysts
Alstrup, I.; Tavares, M. T.; Bernardo, C. A.; Sørensen, O.; Rostrup-Nielsen, J. R.Equilibrium, kinetic and morphological studies of carbon formation in CH4+H2, CO, and CO+H2 gases on silica supported nickel and nickel-copper catalysts are reviewed. The equilibrium deviates in all cases from graphite equilibrium and more so in CO+CO2 than in CH4+H2. A kinetic model based on information from surface science results with chemisorption of CH4 and possibly also the first dehydrogenation step as r...
Data: 1998
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Origem: RepositóriUM - Universidade do Minho
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