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Mutual diffusion of sodium hyaluranate in aqueous solutions
Veríssimo, Luís M. P.; Valada, Teresa I. C.; Sobral, Abilio J. F. N.; Azevedo, Eduarda E. F. G.; Azevedo, Maria L. G.; Ribeiro, Ana C. F.The Taylor dispersion technique has been used for measuring mutual diffusion coefficients of sodium hyaluronate in aqueous solutions at T = 298.15 K, and concentrations ranging from (0.00 to 0.50) g · dm−3. The results are interpreted on the basis of Nernst, and Onsager and Fuoss theoretical equations. From the diffusion coefficient at infinitesimal concentration, the limiting ionic conductivity and the tracer ...
Diffusion of levodopa in aqueous solutions of hydrochloric acid at 25 °C
Barros, Marisa C. F.; Ribeiro, Ana C. F.; Esteso, Miguel A.; Lobo, Victor M. M.; Leaist, Derek G.Ternary mutual diffusion coefficients (D11, D22, D12 and D21) measured by the Taylor dispersion method are reported for aqueous solutions of {levodopa (l-dopa) + HCl} solutions at 25 °C and HCl concentrations up to 0.100 mol · dm−3. The coupled diffusion of l-dopa (1) and HCl (2) is significant, as indicated by large negative cross-diffusion coefficients. D21, for example, reaches values that are larger than D1...
Interaction between lactose and cadmium chloride in aqueous solutions as seen b...
Verissimo, Luis M. P.; Gomes, Joselaine C. S.; Romero, Carmen; Esteso, Miguel A.; Sobral, Abilio J. F. N.; Ribeiro, Ana C. F.Diffusion coefficients of an aqueous system containing cadmium chloride 0.100 mol · dm−3 and lactose at different concentrations at 25 °C have been measured, using a conductimetric cell and an automatic apparatus to follow diffusion. The cell relies on an open-ended capillary method and a conductimetric technique is used to follow the diffusion process by measuring the resistance of a solution inside the capill...
Binary Mutual Diffusion Coefficients of Isoniazid Aqueous Solutions at (298.15 ...
Ribeiro, Ana C. F.; Santos, Ana C. G.; Lobo, Victor M. M.; Veiga, Francisco J. B.; Cabral, Ana M. T. D. P. V.; Esteso, Miguel A.; Ortona, OrnellaBinary mutual diffusion coefficients measured by the Taylor dispersion method in two different laboratories (University of Naples, Federico II, Italy, and University of Coimbra, Portugal) are reported for aqueous solutions of isoniazid at concentrations from (0.000 to 0.100) mol·dm−3 and at two temperatures (298.15 and 310.15) K. The hydrodynamic radii for the isoniazid in aqueous solution are calculated from t...
Aggregation and micellization of sodium dodecyl sulfate in the presence of Ce(I...
Valente, Artur J. M.; Burrows, Hugh D.; Cruz, Sandra M. A.; Pereira, Rui F. P.; Ribeiro, Ana C. F.; Lobo, Victor M. M.Aggregation properties of sodium dodecyl sulfate (SDS) in the presence of cerium(III) chloride, at various temperatures (298.15-323.15 K) have been measured by the electrical conductance technique. The experimental data on aqueous solutions as a function of SDS concentration show the presence of two inflexion points indicating the presence of two distinct interaction mechanisms: the first, occurring at SDS conc...
Mean distance of closest approach of ions: Lithium salts in aqueous solutions
Ribeiro, Ana C. F.; Lobo, Victor M. M.; Burrows, Hugh D.; Valente, Artur J. M.; Amado, Ana M.; Sobral, Abílio J. F. N.; Teles, Ana S. N.Numerical values for the mean distance of closest approach of ions, "a", for lithium salts in aqueous solutions are presented and discussed. These values were obtained from both experimental activity and diffusion coefficients, and estimated by using different theoretical approaches. ; http://www.sciencedirect.com/science/article/B6TGR-4RR1NKM-1/1/b8d3cdac33991c5424d567940bc0c3a6
Diffusion coefficients and electrical conductivities for calcium chloride aqueo...
Ribeiro, Ana C. F.; Barros, Marisa C. F.; Teles, Ana S. N.; Valente, Artur J. M.; Lobo, Victor M. M.; Sobral, Abílio J. F. N.; Esteso, M. A.http://www.sciencedirect.com/science/article/B6TG0-4T7XGV2-6/2/9f2789c31efbabbadc8d9358c079cafe
Some Transport Properties of γ-Cyclodextrin Aqueous Solutions at (298.15 and 31...
Ribeiro, Ana C. F.; Santos, Cecília I. A. V.; Valente, Artur J. M.; Ascenso, Osvaldo S.; Lobo, Victor M. M.; Burrows, H. D.; Cabral, Ana M. T. D. P. V.Values of binary mutual diffusion (interdiffusion) coefficients, obtained by using the Taylor dispersion method, for aqueous solutions of γ-cyclodextrin in the concentration range from (0.002 to 0.010) mol·dm−3 and temperatures (298.15 and 310.15) K are reported. From these experimental results, the hydrodynamic radius values for the γ-cyclodextrin are estimated. Also, the measured diffusion coefficients are us...
Mean distance of closest approach of ions: Sodium salts in aqueous solutions
Ribeiro, Ana C. F.; Esteso, Miguel A.; Lobo, Victor M. M.; Burrows, Hugh D.; Amado, Ana M.; Costa, António M. Amorim da; Sobral, Abílio J. F. N.The estimation of numerical values for the mean distance of closest approach of ions, a, of sodium salts in aqueous solutions, determined from activity and diffusion coefficients, and also from different theoretical approaches, is presented and discussed. ; http://www.sciencedirect.com/science/article/B6TGR-4JCCFW7-1/1/45bf32523013b068b5040514add5505a
Binary Mutual Diffusion Coefficients of Aqueous Solutions of Sucrose, Lactose, ...
Ribeiro, Ana C. F.; Ortona, Ornella; Simões, Susana M. N.; Santos, Cecília I. A. V.; Prazeres, Pedro M. R. A.; Valente, Artur J. M.; Lobo, Victor M. M.Binary mutual diffusion coefficients measured by the Taylor dispersion method in two different laboratories (University of Naples, Federico II, Italy, and University of Coimbra, Portugal) are reported for aqueous solutions of lactose, sucrose, glucose, and fructose at various concentrations (0.001 to 0.1) mol·dm-3 and temperatures (298.15 to 328.15) K. The hydrodynamic radius and activation energy for the diffu...
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