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Analysis of lanthanide induced NMR shifts using a crystal field independent met...

The linear graphical analysis of the LIS NMR data available for the axially symmetric complexes [Ln(DOTA)]- (M and m isomers), [Ln(DOTP)]5- (pH 10.0, 7.0 and 3) and [Ln(DOTEA)]3+ using the classical crystal field dependent method and a crystal field independent method were compared. As the second method provides ratios of geometric structural terms G rather than G values, the effect of lanthanide contraction wa...