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Lousal, Portugal : património geológico e mineiro de uma antiga mina na Faixa P...

Water management in a passive direct methanol fuel cell

Passive direct methanol fuel cells (DMFCs) are under development for use in portable applications because of their enhanced energy density in comparison with other fuel cell types. The most significant obstacles for DMFC development are methanol and water crossover because methanol diffuses through the membrane generating heat but no power. The presence of a large amount of water floods the cathode and reduces ...

Simulation of a stand-alone residential PEMFC power system with sodium borohydr...

Catalytic hydrolysis of sodium borohydride (NaBH4) has been investigated as a method to generate hydrogen for fuel cell applications. The high purity of the generated hydrogen makes this process a potential source of hydrogen for polymer electrolyte membrane fuel cells (PEMFCs). In this paper, a PEMFC power system employing a NaBH4 hydrogen generator is designed to supply continuous power to residential power ...

Experimental and modeling studies of a micro direct methanol fuel cell

The Direct Methanol Fuel Cell (DMFC) has attracted much attention due to its potential applications as a power source for transportation and portable electronic devices. Based on the advantages of the scaling laws, miniaturization promises higher efficiency and performance of power generating devices and the MicroDMFC is therefore an emergent technology. In this work, a set of experiences with a MicroDMFC of 2....

Micro direct methanol fuel cell: experimental and modelling studies

The Direct Methanol Fuel Cell (DMFC) has attracted much attention due to its potential applications as a power source for transportation and portable electronic devices. Based on the advantages of the scaling laws, miniaturization promises higher efficiency and performance of power generating devices and the MicroDMFC is therefore an emergent technology. In this work, a set of experiences with a MicroDMFC of 2....

Hydrogen generation by borohydrides: critical issues for portable applications

High volumetric and gravimetric efficiency are key to potential hydrogen energy carriers. Sodium borohydride emerges as such potentiality and a storage capacity well within DOE targets for 2015. Limitations exist due to the fact that hydrolysis is restricted by available water and due to the lack of low cost re-usable catalysts. An extensive amount of work has been done in our laboratories on Ni and Ru based ca...

Influence of indirect ultrasonic vibration on the microstructure and mechanical...

The influence of high intensity ultrasound (US) propagating through a steel mold on the microstructure and mechanical properties of die-cast AlSi9Cu3, for different levels of electric power and at different distances to the waveguide/mold interface. The influence of those parameters on the morphology of -Al and eutectic Si and on the volume of porosity were investigated and characterized. The morphological ch...

Simulation of the nucleation of the precipitate Al3Sc in an aluminum scandium a...

Low density, high strength to corrosion and specific strength to weight ratio are properties that made aluminum alloys excellent materials for transportation industry. A promising way to develop ultra-high strength aluminum alloys is achieved by the addition of metallic elements with low solubility in aluminum, promoting the Al3X (X = Sc) nanoparticles formation. Moreover, Al alloys have applications in the aer...

The effect of Sc additions on the microstructure and age hardening behaviour of...

The grain refinement effect and the ageing behaviour of Al–0.5 wt.% Sc, Al–0.7 wt.% Sc, and Al–1 wt.% Sc alloys are studied on the basis of optic microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD) observations and hardness measurements. In Al–Sc alloys the higher grain refinement is observed for Sc contents greater than 0.5 wt.% accompanied by a notorious morphology modification, from ...

Current density distribution mapping in polymer electrolyte membrane fuel cell

A non-uniform utilization of the active area due to inhomogeneous current density distribution is one of the main factors for poor fuel cell performance. Furthermore, it leads to hot points which can be responsible for thermal stress in the membrane electrode assemble (MEA). Therefore, it became extremely important to have a consistent technic to visualize in real time the current density and temperature distri...