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Carbon based materials as novel redox mediators for dye wastewater biodegradation

Pereira, Raquel; Pereira, M. F. R.; Alves, M. M.; Pereira, Luciana

Due to their large-scale production and extensive application, dyes have turned serious pollutants when improperly handled and disposed, creating grave public health and environmental problems. One of the problems that textile industry is facing is related with the incomplete exhaustion of dyes onto textile fibres from an aqueous dyeing process, and the need to implement innovative and sustainable effluent trea...


Evaluation of ion exchange-modified Y and ZSM5 zeolites in Cr(VI) biosorption a...

Silva, Bruna; Figueiredo, Hugo; Soares, O. S. G. P.; Pereira, M. F. R.; Figueiredo, J. L.; Lewandowska, A. E.; Bañares, M. A.; Bañares, M. A.

The aim of this work was the evaluation of the performance of two zeolites with different structures (FAU and MFI) and acidity properties in the biosorption of Cr(VI) and catalytic oxidation of ethyl acetate. The starting zeolites, Y (FAU) and ZSM5 (MFI), were modified by ion exchange treatments with NaNO3 in order to obtain zeolites with different acidity and sodium content. A biosorption system consisting of ...


Electrocatalytic oxidation of oxalic and oxamic acids in aqueous media at carbo...

Ferreira, Marta; Pinto, Mara F.; Soares, O. S. G. P.; Pereira, M. F. R.; Orfão, J. J. M.; Figueiredo, J. l.; Neves, Isabel C.; Fonseca, A. Maurício C.

The electrochemical oxidation of oxalic and oxamic acids on multiwalled carbon nanotubes (CNT) and on monometallic (Pd and Pt) and bimetallic (Pd-Cu, Pt-Cu) catalysts supported on multiwalled carbon nanotubes was investigated using cyclic voltammetry. The electrodes were prepared by dispersion of the catalytic material on Toray carbon (CT) using a Nafion/water solution. The kinetic parameters of the reactions w...


The effect of nanotube surface oxidation in the electrical response of MWCNT/PV...

Lanceros-Méndez, S.; Carabineiro, S. A. C.; Pereira, M. F. R.; Caparrós Vásquez, Cristina Maria; Pereira, J. Nunes; Sencadas, V.; Silva, J.

Carbon nanotubes / poly(vinylidene fluoride) composites were prepared using CNT with different oxidation and thermal treatments. The oxidation procedure leads to CNT with the most acidic characteristics that lower the degree of crystallinity of the polymer and contribute to a large increase of the dielectric constant. The surface treatments, in general, increase percolation threshold and decrease conductivity, ...


Evaluation of ion exchange-modified Y and ZSM5 zeolites in Cr(VI) biosorption a...

Silva, Bruna; Figueiredo, Hugo; Soares, O. S. G. P.; Pereira, M. F. R.; Figueiredo, J. L.; Lewandowska, A. E.; Bañares, M. A.; Neves, Isabel C.

The aim of this work is the evaluation of the performance of two zeolites with different structures (FAU and MFI) and acidity properties in the biosorption of Cr(VI) and catalytic oxidation of ethyl acetate. The starting zeolites, Y (FAU) and ZSM5 (MFI), were modified by ion exchange treatments with NaNO3 in order to obtain zeolites with different acidity and sodium content. A biosorption system consisting of a...


Influence of the support characteristics and their functionalization on the cat...

Calderon, J. C.; Figueiredo, J. L.; Mahata, N.; Pereira, M. F. R.; Fernandes, Vitor R.; Rangel, C. M.; Pastor, E.; Calvillo, L.; Lázaro, M. J.

Data: 2011   |   Origem: Repositório do LNEG

Influence of catalyst support characteristics and functionalization on the cata...

Calderon, J. C.; Figueiredo, J. L.; Mahata, N.; Pereira, M. F. R.; Fernandes, Vitor R.; Rangel, C. M.; Calvillo, L.; Lázaro, M. J.; Pastor, E.

Pt-Ru electrocatalysts supported on carbon xerogels and ordered mesoporous carbons were synthesized by reduction with formate ions (SFM method). Chemical and heat treatments were applied to modified the surface chemistry of original carbon supports. Physical characterization of the catalysts was performed using X-ray dispersive energy (EDX) and X-ray diffraction (XRD) techniques, while the electrochemical activ...

Data: 2011   |   Origem: Repositório do LNEG

Influence of catalyst support characteristics and functionalization on the cat...

Calderon, J. C.; Figueiredo, J. L.; Mahata, N.; Pereira, M. F. R.; Fernandes, Vitor R.; Rangel, C. M.; Calvillo, L.; Lázaro, M. J.; Pastor, E.

Pt-Ru electrocatalysts supported on carbon xerogels and ordered mesoporous carbons were synthesized by reduction with formate ions (SFM method). Chemical and heat treatments were applied to modified the surface chemistry of original carbon supports. Physical characterization of the catalysts was performed using X-ray dispersive energy (EDX) and X-ray diffraction (XRD) techniques, while the electrochemical activ...

Data: 2011   |   Origem: Repositório do LNEG

Reutilization of Cr-Y zeolite obtained by biosorption in the catalytic oxidatio...

Silva, Bruna; Figueiredo, Hugo; Santos, V. P.; Pereira, M. F. R.; Figueiredo, J. L.; Lewandowska, A. E.; Bañares, M. A.; Neves, Isabel C.

This work aims at the reutilization of a Cr-loaded NaY zeolite obtained by biorecovery of chromium from water as catalyst in the oxidation of volatile organic compounds (VOC). Cr-NaY catalysts were obtained after biosorption of Cr(VI) using a bacterium, Arthrobacter viscosus, supported on the zeolite. The biosorption experiments were conducted at different pH values in the range 1–4. The catalysts were characte...


Pt-Ru Catalysts supported on mesoporous carbons for polymer electrolyte membran...

Calderon, J. C.; Figueiredo, J. L.; Mahata, N.; Pereira, M. F. R.; Fernandes, Vitor R.; Rangel, C. M.; Pastor, E.; Calvillo, L.; Lázaro, M. J.

Pt-Ru electrocatalysts supported on xerogels and CMK-3 ordered mesoporous carbons were synthesized by reduction with formate ions (SFM method). Some of the carbon supports were chemically treated with HNO3 in order to generate oxygen groups on the surface, while other supports were heat treated. Physical characterization of the catalyst was obtained using X-ray dispersive energy (EDX) and X-ray diffraction (XRD...

Data: 2010   |   Origem: Repositório do LNEG

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    Financiadores do RCAAP

Fundação para a Ciência e a Tecnologia Universidade do Minho   Governo Português Ministério da Educação e Ciência Programa Operacional da Sociedade do Conhecimento União Europeia