Dissertação de mestrado em Engenharia de Materiais ; Na vasta gama dos polímeros, o poli(fluoreto de vinilideno) (PVDF), é o que reúne as propriedades piezo, piro e ferroeléctricas mais interessantes do ponto de vista científico e tecnológico. Assim sendo, o objectivo deste trabalho consistiu em estudar e caracterizar a resposta piezoeléctrica deste polímero, quer na escala microscópica quer na macroscópica, r...
Chain reorientation may be induced in polyvinylidene fluoride (PVDF) in its β-phase by applying a deformation perpendicular to the pre-oriented polymeric chains. This reorientation begins right after the yielding point and seems to be completed when the stress-strain curve stabilizes. As the deformation process plays an important role in the processing and optimisation properties of the material for practical a...
The phase diagram of the poly(vinylidene fluoride-trifluorethylene) (P(VDF-TrFE)) copolymer system shows for VDF contents of 50...85 mol% a ferroelectric (FE)-paraelectric (PE) phase transition below melting temperature. Investigations on P(VDF-TrFE) 75/25 samples revealed a slight anisotropic behaviour, which leads to a strongly anisotropic stretching effect both on the phase transition and on the amount and n...
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