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Self-structuring of lamellar bridged silsesquioxanes with long side spacers
Fernandes, M.; Nobre, S. S.; Xu, Q. H.; Carcel, C.; Cachia, J. N.; Cattoen, X.; Sousa, J. M.; Ferreira, R. A. S.; Carlos, L. D.; Santilli, C. V.Diurea cross-linked bridged silsesquioxanes (BSs) C(10)C(11)C(10) derived from organosilane precursors, including decylene chains as side spacers and alkylene chains with variable length as central spacers (EtO)(3)Si- (CH(2))(10)-Y(CH(2))(n)-Y-(CH(2))(10)-Si(OEt)(3) (n = 7, 9-12; Y = urea group and Et = ethyl), have been synthesized through the combination of self-directed assembly and an acid-catalyzed sol gel...
Data: 2011
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Origem: RIA - Repositório Institucional da Universidade de Aveiro
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