Polímeros reforçados por fibras (PRF) tem sido utilizados durante muito tempo para aplicações estruturais, particularmente com laminados. No projeto de laminados é importante caracterizar o seu comportamento mecânico. O comportamento mecânico é caracterizado por uma rigidez inicial e pela fractura. A estratégia de modelação utilizada nesta dissertação permite não só prever o “first-ply-failure”, como também mod...
It is shown that electrospun poly(vynilidene fluoride) nanofibers are fully poled right after preparation and show b-phase contents of 70%, therefore being able to be implemented into electroactive devices without further processing steps. Further,the local piezoelectric properties of individual electrospun fibers have been studied by piezoresponse force microscopy. Piezoelectric response, polarization switching,...
Cadmium chalcogenide quantum dots (QD's) were synthesised using a single source approach while zinc oxide QD's were obtained by a colloidal technique. In both situations the dots were surface capped with tri-octylphosphine oxide (TOPO) hence leading to nanodispersed systems in organic solvents such as toluene. The organically capped QD's (CdSe, CdS and ZnO) were used as building-units to fabricate LbL (layer-by...
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