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Infrared Spectra and Photochemistry of Matrix-Isolated Pyrrole-2-carbaldehyde
Giuliano, Barbara Michela; Reva, Igor; Fausto, RuiMonomeric pyrrole-2-carbaldehyde (P2C) was isolated in low-temperature argon and xenon matrices, and its UV-induced photochemistry was studied. The structures of the reagent as well as the reaction photoproducts were characterized by FTIR spectroscopy. Interpretation of the experimental results was assisted by theoretical calculations carried out at the MP2 and DFT (B3LYP) levels with the 6-311++G(d,p) basis se...
Data: 2010
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Origem: Estudo Geral - Universidade de Coimbra
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