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Intercalation of a molybdenum η3-allyl dicarbonyl complex in a layered double h...
Gomes, Ana C.; Bruno, Sofia M.; Gamelas, Carla A.; Valente, Anabela A.; Abrantes, Marta; Gonçalves, Isabel S.; Romão, Carlos C.; Pillinger, Martyn
Molybdenum(II) Diiodo-Tricarbonyl Complexes Containing Nitrogen Donor Ligands a...
Gamelas, Carla A.; Neves, P.; Gomes, Ana C.; Valente, Anabela A.; Romão, Carlos C.; Gonçalves, Isabel S.; Pillinger, M.Resumo alargado de "Molybdenum(II) Diiodo-Tricarbonyl Complexes Containing Nitrogen Donor Ligands as Catalyst Precursors for the Epoxidation of Methyl Oleate"
Dichloro and dimethyl dioxomolybdenum(VI)–diazabutadiene complexes as catalysts...
Moreira, José A.; Valente, Anabela A.; Pillinger, Martyn; Nunes, Carla D.; Gonçalves, Isabel S.; Lopes, André D.; Romão, Carlos C.; Kuhn, Fritz E.The dioxomolybdenum(VI) complex [MoO2Cl2{p-tolyl(CH3DAB)}] has been prepared in good yield by reaction of the solvent adduct MoO2Cl2(THF)2 with one equivalent of the bidentate ligand N,N-p-tolyl-2,3-dimethyl- 1,4-diazabutadiene. Treatment of the dichloro complex with the Grignard reagent CH3MgCl gives the dimethyl derivative [MoO2(CH3)2{p-tolyl(CH3DAB)}]. The complexes are highly active and selective catalysts ...
Interactions of Cationic and Neutral Molybdenum Complexes with β-Cyclodextrin H...
Lima, Sérgio; Gonçalves, Isabel S.; Ribeiro-Claro, Paulo; Pillinger, Martyn; Lopes, André D.; Ferreira, Paula; Teixeira-Dias, José J. C.; Rocha, JoãoThe inclusion compounds formed between β-cyclodextrin (β-CD) and the tetrafluoroborate salts [Cp‘Mo(η4-C6H8)(CO)2][BF4] and the neutral derivatives Cp‘Mo(η3-C6H7)(CO)2 [Cp‘ = Cp (η5-C5H5), Ind (η5-C9H7)] were studied by means of elemental analysis, FTIR spectroscopy, thermogravimetric analysis (TGA), powder X-ray diffraction (XRD), and magic-angle spinning (MAS) NMR (13C, 11B). Additional information concerning...
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