Three new lanthanide(III) complexes (Ln = Sm, Tb and Eu) of picolinic and glutaric acid were prepared and characterised. The crystal structure of the complex [Sm(glu)(pic)- (H2O)2] (where Hpic and H2glu stand for picolinic and glutaric acid, respectively) was determined by single-crystal Xray diffraction. All the Ln complexes were characterised by elemental analysis, infrared spectroscopy, X-ray powder diffract...
Non-human primates have constituted an important group among animals subjected to various studies. Ethological, evolutionary and paleontological studies have revealed changes in anatomical structures linked to the evolution of primates, considered in studies on the comparative anatomy between Cebus libidinosus and other neotropical monkeys or those from the Old World, and the detailed knowledge on their anatomy...
New cyano-bridged coordination polymers [Nd(phen)(2)(DMF)(2)(H(2)O)Mo(CN)(8)] center dot 2H(2)O (1) and [Nd(phen)(DMF)(5)M(CN)(8)] center dot xH(2)O [M = Mo (2), W (3); phen = 1,10-phenanthroline] have one-dimensional structures with variable number of phenanthroline ligands. Compounds exhibit photoluminescence in the near-infrared region and ferromagnetic Nd(3+)-M(5+) interactions.
Diurea cross-linked bridged silsesquioxanes (BSs) C(10)C(11)C(10) derived from organosilane precursors, including decylene chains as side spacers and alkylene chains with variable length as central spacers (EtO)(3)Si- (CH(2))(10)-Y(CH(2))(n)-Y-(CH(2))(10)-Si(OEt)(3) (n = 7, 9-12; Y = urea group and Et = ethyl), have been synthesized through the combination of self-directed assembly and an acid-catalyzed sol gel...
In Press; available online 10 November 2011 ; Sol-gel derived KCF3SO3-doped di-urethane cross-linked poly(ε-caprolactone) (PCL(530))/siloxane ormolytes with ∞ > n ≥ 0.5 (n indicates the number of (C(=O)(CH2)5O) repeat units per K+ ion) have been studied. Xerogel samples with n ≥ 1 are thermally stable up to 235 ºC. A minor proportion of PCL crystallites occur in some dilute-to-concentrated samples. At n ≤ 4 a ...
Variable chain length di-urethane cross-linked poly(oxyethylene) (POE)/siloxane hybrid networks were prepared by application of a sol-gel strategy. These materials, designated as di-urethanesils (represented as d-Ut(Y’), where Y’ indicates the average molecular weight of the polymer segment), were doped with lithium triflate (LiCF3SO3). The two host hybrid matrices used, d-Ut(300) and d-Ut(600), incorporate POE...
Durante todas as fases fenológicas do cafeeiro, o clima exerce grande infl uência sobre a incidência de pragas e doenças e, consequentemente, atua sobre a produtividade do cafeeiro e a qualidade da bebida. Adversidades climáticas, como acentuada defi ciência hídrica e extremos de temperatura do ar, podem resultar em redução drástica de produtividade do cafeeiro, embora os efeitos dependam da duração e da intens...
Durante todas as fases fenológicas do cafeeiro, o clima exerce grande infl uência sobre a incidência de pragas e doenças e, consequentemente, atua sobre a produtividade do cafeeiro e a qualidade da bebida. Adversidades climáticas, como acentuada defi ciência hídrica e extremos de temperatura do ar, podem resultar em redução drástica de produtividade do cafeeiro, embora os efeitos dependam da duração e da intens...
A Embrapa Arroz e Feijão desenvolveu algumas linhagens de arroz preto com grão similar ao tipo agulhinha e realizou alguns estudos agronômicos e de qualidade de grãos com o objetivo de estimular a ampliação de novos mercados para os produtores atingirem um nicho específico, com potencial no consumo interno e externo, já que o arroz preto tem amplo mercado na Europa e nos Estados Unidos. Apesar de ainda incipien...
POCI/QUI/58377/2004 - FEDER ; SFRH/BPD/9309/2002 (to F.-N.S.) ; SFRH/BPD/14410/2003 (to L.C.-S.) ; NoE FAME
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