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Novel highly emissive non proteinogenic amino acids : synthesis of 1,3,4-thiadi...

Esteves, Cátia I. C.; Raposo, M. Manuela M.; Costa, Susana P. G.

Highly emissive heterocyclic asparagine derivatives bearing a 1,3,4-thiadiazolyl unit at the side chain, functionalised with electron donor or acceptor groups, were synthesised and evaluated as amino acid based fluorimetric chemosensors for metal cations such as Cu2+, Zn2+, Co2+ and Ni2+. The results suggest that there is a strong interaction through the donor heteroatoms at the side chain of the various aspara...


Unnatural benz-X-azolyl asparagine derivatives as novel fluorescent amino acids...

Esteves, Cátia I. C.; Silva, Ana M. F.; Raposo, M. Manuela M.; Costa, Susana P. G.

A family of new asparagine derivatives bearing benzothiazole and benzimidazole units, functionalised with electron donor or acceptor groups, were synthesized in good to excellent yields. The photophysical characterization of these new heterocyclic amino acids was performed by UV-visible absorption and fluorescence emission studies and revealed that the compounds displayed remarkably high fluorescence quantum yi...


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Fundação para a Ciência e a Tecnologia Universidade do Minho   Governo Português Ministério da Educação e Ciência Programa Operacional da Sociedade do Conhecimento União Europeia