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Fast and Slow Time Regimes of Fluorescence Quenching in Conjugated Polyfluorene...
Dias, Fernando B.; Knaapila, Matti; Monkman, Andrew P.; Burrows, Hugh D.The luminescence decay kinetics of polyfluorene copolymers containing fluorenone units randomly distributed along the polymer chain have been studied by steady-state and time-resolved fluorescence techniques in toluene solution. The typical green emission from polyfluorenes containing 9-fluorenone moieties is only observed if the 9-fluorenone group is covalently attached to the polymer. Small-angle neutron scat...
Kinetics and Thermodynamics of Poly(9,9-dioctylfluorene) β-Phase Formation in D...
Dias, Fernando B.; Morgado, Jorge; Maçanita, António L.; Costa, Fernando P. da; Burrows, Hugh D.; Monkman, Andrew P.Poly(9,9-dioctylfluorene) (PFO) adopts a particular type of conformation in dilute solutions of the poor solvent methylcyclohexane (MCH) below 273 K, which is revealed by the appearance of a red-shifted absorption peak at 437−438 nm. The formation of this ordered conformation depends on the temperature but is independent of polymer concentration over the range studied (3−25 μg/mL). On the basis of absorption, s...
Kinetics and thermodynamics of poly (9,9-dioctylfluorene) beta-phase formation ...
Costa, Fernando Pestana da; Maçanita, António L.; Morgado, Jorge; Dias, Fernando B.; Burrows, Hugh D.; Monkman, Andrew P.Poly(9,9-dioctylfluorene) (PFO) adopts a particular type of conformation in dilute solutions of the poor solvent methylcyclohexane (MCH) below 273 K, which is revealed by the appearance of a red-shifted absorption peak at 437−438 nm. The formation of this ordered conformation depends on the temperature but is independent of polymer concentration over the range studied (3−25 μg/mL). On the basis of absorption, s...
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