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Hyperthermia induced after recirculation triggers chronic neurodegeneration in ...

Favero-Filho,L.A.; Borges,A.A.; Grassl,C.; Lopes,A.C.; Sinigaglia-Coimbra,R.; Coimbra,C.G.

Chronic neurodegenerative processes have been identified in the rat forebrain after prolonged survival following hyperthermia (HT) initiated a few hours after transient global ischemia. Since transient global ischemia and ischemic penumbra share pathophysiological similarities, this study addressed the effects of HT induced after recirculation of focal brain ischemia on infarct size during long survival times. ...

Data: 2008   |   Origem: OASIS br

Photodegradation of atrazine and ametryn with visible light using water soluble...

Rebelo, Susana; Melo, A.; Coimbra, R.; Azenha, M.; Pereira, Mariette; Burrows, Hugh; Sarakha, Mohamed

Abstract The photodegradation of the herbicides atrazine and ametryn with visible light in aerated neutral aqueous solutions and 5, 10, 15, 20-tetrakis (2,6-dichloro-3-sulfophenyl) porphyrin or 5, 10, 15, 20-tetrakis (4-sulfophenyl) porphyrin as sensitizers are reported for the first time. Our findings show that the degradation percentage reached 30% for atrazine and 63% for ametryn. The final photoproducts we...


Kinetic and mechanistic aspects of the direct photodegradation of atrazine, atr...

Azenha, M. E. D. G.; Burrows, H. D.; L., M. Canle; Coimbra, R.; Fernández, M. I.; García, M. V.; Peiteado, M. A.; Santaballa, J. A.

Atrazine (1), Atraton (2) and Ametryn (3) are photodegraded upon 254 nm irradiation, yielding 2-OH-atrazine (4) as a photoproduct. Dealkylation products are also generated, and 4-ethylamino-6-isopropylamino-(1,3,5)-triazine was also found as a photoproduct of 3. The main photoreaction is proposed to be an addition-elimination, yielding 4, which subsequently photodegrades. The ease of photodegradation depends on...



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Fundação para a Ciência e a Tecnologia Universidade do Minho   Governo Português Ministério da Educação e Ciência Programa Operacional da Sociedade do Conhecimento União Europeia