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Synthesis, reactivity and catalytic properties of rhodium complexes of (R,R)-1-...
Diéguez, M.; Ruiz, A.; Claver, C.; Pereira, M. M.; Flor, M. T.; Bayón, J. C.; Serra, M. E. S.; Rocha Gonsalves, A. M. d'A.Complexes [Rh(cod)(degusR)]ClO4, where cod is 1,5-cyclooctadiene and degusR represents the homochiral dithioethers (R,R)-1-benzyl-3,4-bis(methylsulfanyl)pyrrolidine, (R,R)-1-benzyl-3,4-bis(isopropylsulfanyl)pyrrolidine and (R,R)-1-benzyl-3,4-bis(phenylsulfanyl)pyrrolidine were prepared and characterized. Their reactivity with CO and PPh3 was investigated. The complexes were assayed as catalysts in hydroformylat...
Data: 1999
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Origem: Estudo Geral - Universidade de Coimbra
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