We present herein results on the PhSeBr-catalyzed addition of thiols to α,β-unsaturated carbonyl compounds under mild conditions to afford regioselectivily β-mercapto ketones or thioacetals in high yields and selectivity. The reaction was highly controlled by the temperature in which, the 1,4-addition products were obtained when the temperature was -20 ºC, conversely when the reaction was carried...
In recent years, the interest in the practical applications of local people's knowledge has been renewed. The potential uses of ethnobotanical information can be used for new marketable purposes. In order to keep alive the ancient relationship of useful flora amongst our people, we carried out ethno-botanical research in the Center of Portugal (Santarem). Useful plants and traditional remedies and other uses ar...
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