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Self-aggregation of free base porphyrins in aqueous solution and in DMPC vesicles

Andrade, Suzana M.; Teixeira, Raquel; Costa, Sílvia M.B.; Sobral, Abílio J.F.N.

Free base porphyrin (PPhe), derivatized with aminosulfonyl groups linked to the aromatic amino acid phenylalanine at the meso-positions, was mixed with DMPC vesicles. The resulting interaction was studied by absorption, steady-state and transient state fluorescence, at different pHs. ; http://www.sciencedirect.com/science/article/B6TFB-4R68NKV-2/1/aca6e255f297903981898ccea264a386


Self-association of free base porphyrins with aminoacid substituents in AOT rev...

Andrade, Suzana M.; Teixeira, Catarina; Togashi, Denisio M.; Costa, Sílvia M.B.; Sobral, Abílio J.F.N.

The aggregation properties of aminosulfonyl porphyrins with aminoacid substituents: methionine with the acid function methylated, PMetCH3; phenylalanine, PPhe; attached to the para positions of the meso phenyls of the porphyrin, was followed in organic solvents, water-dioxane mixtures and in reverse micelles of aerosol OT (AOT RM), using absorption, steady-state and time-resolved fluorescence. In AOT RM in the ...


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