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Synthesis and characterization of the thermal and the solvatochromic properties...

Raposo, M. Manuela M.; Ferreira, Ana M. P. F.; Amaro, Mariana; Belsley, M.; Moura, João C. V. P.

A series of heterocyclic azo dyes was synthesized by diazotation of several substituted anilines and coupling with 5-N,N-dialkylamino-2,2´-bithiophenes to give 4-phenylazo-5-N,N-dialkylamino-2,2´-bithiophenes 4-7. This reaction contrasts with the behavior of 5-alkoxy-2,2´-bithiophenes towards aryldiazonium salts which gave 5-phenylazo-5-alkoxy-2,2´-bithiophenes. The thermal stability of the derivatives was eval...


Controllable transport mean free path of light in xerogel matrixes embedded wit...

Bret, Boris P. J.; Couto, Nuno J. G.; Amaro, Mariana; Pereira, E. N. B.; Belsley, M.

Xerogel matrices, made by sol-gel techniques, are embedded with polystyrene spheres to promote multiple scattering of light. Varying the concentration of the spheres inside the matrix allows one to adjust the transport mean free path of light inside the material. Coherent backscatte- ring measurements show that a range of transport mean free paths from 90 to 600 um is easily achieved. The determination of the m...


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Fundação para a Ciência e a Tecnologia Universidade do Minho   Governo Português Ministério da Educação e Ciência Programa Operacional da Sociedade do Conhecimento União Europeia