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A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [P...
Paz, FAA; Sousa, FL; Soares-Santos, PCR; Cavaleiro, AMV; Nogueira, HIS; Klinowski, J; Trindade, TThe structure of the title compound, tris(hydroxonium) 12- phosphato-tetracosa- 2-oxo-dodecaoxododecatungsten hexakis( benzo-15-crown-5)±methanol±water (1/1/1), (H3O)3- [PW12O40] 6C14H20O5 CH3OH H2O (where C14H20O5 is benzo-15-crown-5), has been determined at 180 K. [PW12O40]3ÿ anions are typical of -Keggin structures, and the [H3O (C14H20O5)2]+ sandwich-type moieties contain a large number of short O O c...
Data: 2004
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Origem: RIA - Repositório Institucional da Universidade de Aveiro
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