Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-aziri...

• Autor(es): Lemos, A. ; Guimaraes, Emanuel ; Fortes, Gil ; Alves, Maria José Chão
• Data: 2003
• Identificador Persistente: http://hdl.handle.net/10400.1/1023
• Origem: Sapientia - Universidade do Algarve
• Assunto(s): Azirinas; Heterocycles; Intermolecular radical addition; Triethylborane; Alfa-aminoesters
• Tipo de Documento: Artigo
• Idioma: Inglês

Descrição

The 2H-azirine 1 acts as an effective radical acceptor for secondary and tertiary alkyl iodides mediated by triethylborane. The addition proceeds with high regio- and diastereo-selectivity.