Near-infrared luminescent and magnetic cyano-bridged coordination polymers Nd(p...

• Author(s): Long, J. ; Chelebaeva, E. ; Larionova, J. ; Guari, Y. ; Ferreira, R. A. S. ; Carlos, L. D. ; Paz, F. A. A. ; Trifonov, A. ; Guerin, C.
• Date: 2011
• Persistent ID: http://hdl.handle.net/10773/6303
• Origin: RIA - Repositório Institucional da Universidade de Aveiro
• Document Type: Article
• Language: English

Description

New cyano-bridged coordination polymers [Nd(phen)(2)(DMF)(2)(H(2)O)Mo(CN)(8)] center dot 2H(2)O (1) and [Nd(phen)(DMF)(5)M(CN)(8)] center dot xH(2)O [M = Mo (2), W (3); phen = 1,10-phenanthroline] have one-dimensional structures with variable number of phenanthroline ligands. Compounds exhibit photoluminescence in the near-infrared region and ferromagnetic Nd(3+)-M(5+) interactions.