Author(s):
Paz, FAA 
; Neves, MC ; Trindade, T ; Klinowski, J
Date: 2003
Persistent ID: http://hdl.handle.net/10773/5978
Origin: RIA - Repositório Institucional da Universidade de Aveiro
Document details
The first dinuclear zinc(II) dithiocarbarnate complex with butyl substituent gr...
Description
The crystal structure of the title compound, bis( -N,N- dibutyldithiocarbamato- 2S:S0)bis[(N,N-dibutyldithiocarba\- forcelb]mato- 2S,S0)zinc(II)], [Zn2(C9H18NS2)4], has been determined at 180 K. The structure contains two crystallographically unique Zn2+ metal centres, showing almost identical slightly distorted tetrahedral coordination environments, and forming a dinuclear complex with two skew-bridging syn-N,N-dibutyldithiocarbamate ligands. Two other dithiocarbamate ligands are connected to the Zn2+ centres in a syn,syn-chelate coordination mode.
The crystal structure of the title compound, bis( -N,N- dibutyldithiocarbamato- 2S:S0)bis[(N,N-dibutyldithiocarba\- forcelb]mato- 2S,S0)zinc(II)], [Zn2(C9H18NS2)4], has been determined at 180 K. The structure contains two crystallographically unique Zn2+ metal centres, showing almost identical slightly distorted tetrahedral coordination environments, and forming a dinuclear complex with two skew-bridging syn-N,N-dibutyldithiocarbamate ligands. Two other dithiocarbamate ligands are connected to the Zn2+ centres in a syn,syn-chelate coordination mode.
Document Type
Article
Language English
Language English
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