Author(s):
Shi, Fa-Nian 
; Trindade, Tito ; Rocha, João ; Paz, Filipe A. Almeida
Date: 2008
Persistent ID: http://hdl.handle.net/10773/5889
Origin: RIA - Repositório Institucional da Universidade de Aveiro
Document details
Hydro-ionothermal synthesis of lanthanide-organic frameworks with 1,4-phenylene...
Description
A synthetic approach combining hydrothermal and ionothermal (eutectic mixture of choline chloride and malonic acid) procedures is proposed that allowed the isolation of the first lanthanide-organic frameworks with residues of 1,4-phenylenebis(methylene)- diphosphonic acid (H4pmd), [Ln(Hpmd)(H2O)] (where Ln3+ ) Ce3+ and Pr3+), exhibiting an unprecedented trinodal topology with 3- and 8-connected nodes. The structural details were unveiled from single-crystal X-ray diffraction and the materials were characterized using standard techniques. FCT - POCI-PPCDT/QUI/58377/2004 FEDER - POCI Grant - SFRH/BPD/9309/2002
A synthetic approach combining hydrothermal and ionothermal (eutectic mixture of choline chloride and malonic acid) procedures is proposed that allowed the isolation of the first lanthanide-organic frameworks with residues of 1,4-phenylenebis(methylene)- diphosphonic acid (H4pmd), [Ln(Hpmd)(H2O)] (where Ln3+ ) Ce3+ and Pr3+), exhibiting an unprecedented trinodal topology with 3- and 8-connected nodes. The structural details were unveiled from single-crystal X-ray diffraction and the materials were characterized using standard techniques. FCT - POCI-PPCDT/QUI/58377/2004 FEDER - POCI Grant - SFRH/BPD/9309/2002
Document Type
Article
Language English
Language English
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