Spectrophotometric flow system using vanadomolybdophosphate detection chemistry...

• Autor(es): Neves, M. Sofia A. C. ; Souto, M. Renata S. ; Tóth, lldikó V. ; Victal, Sérgio M. A. ; Drumond, M. Cláudia ; Rangel, António O. S. S.
• Data: 2008
• Identificador Persistente: http://hdl.handle.net/10400.14/2761
• Origem: Veritati - Repositório Institucional da Universidade Católica Portuguesa
• Assunto(s): Phosphate determination; Flow injection; Liquid waveguide capillary cell; Long pathlength spectrophotometry; Silicate interference
• Tipo de Documento: Artigo
• Idioma: Inglês

Descrição

reactive phosphorus in water samples is described. The system includes a liquid waveguide long pathlength cell connected to a charge coupled device (CCD) spectrophotometer. Calibration was linear up to 500 µgPL−1, with a detection limit of 17 µgPL−1 and a quantification limit of 56 µgPL−1. An injection throughput of 60 determinations h−1 and repeatability (R.S.D.) of 2.2% were achieved. Potential interference from silicate was effectively masked by addition of a tartaric acid stream. The accuracy of the proposedmethodology was assessed through analysis of a certified reference material and recovery tests on water samples. The developed procedure allows the determination of phosphorus in water samples at trace levels with high sensitivity, reduced reagent consumption and low waste production.