A ternary phase in Cu-Li-Mg system

• Author(s): Maria Helena Sousa Soares de Oliveira Braga ; J. Ferreira ; Luís Filipe Malheiros de Freitas Malheiros
• Date: 2007
• Persistent ID: http://hdl.handle.net/10216/67196
• Origin: Repositório Aberto da Universidade do Porto
• Subject(s): Ciências Físicas; Física
• Document Type: Article
• Language: Portuguese

Description

A previous study on Cu–Li–Mg system pointed out the existence of Cu8Li2Mg15, with an orthorhombic structure. The authors of the present paper also detected the existence of a ternary phase similar to the one mentioned. Due to some doubts on the phase’s structure, a study of Cu–Li–Mg was focused in an area near to the composition of that phase. SEM/EDS measurements of the phases’ compositions in equilibrium, as well as XRD powder patterns were obtained at room temperature. It was concluded that the ternary phase in Cu–Li–Mg system corresponds to CuMg2−xLix (x≈0.11), with a hexagonal structure, space group P6222 (1 8 0), and lattice parameters a = b = 0.5260 nm, and c = 1.3649 nm. The structure was refined by Rietveld method; a Bragg reliability factor RB = 6.36% was obtained. Similarities between CuMg2−xLix (x≈0.11) and NiMg2(H, D)x (x≈0.3) structures are detailed.