Author(s):
Sobral, Abílio J. F. N. 
; Gonsalves, António M. d'A. Rocha
Date: 2001
Persistent ID: http://hdl.handle.net/10316/8300
Origin: Estudo Geral - Universidade de Coimbra
Document details
The manganese complex of 2,3,7,8,12,13,17,18-octaphenylporphyrin as epoxidation...
Description
The 2,3,7,8,12,13,17,18-octaphenylporphyrinato manganese(III) chloride was prepared and its behaviour as epoxidation catalyst was studied. The role of the phenyl substituents in the ß-pyrrolic positions concerning the stability of the catalyst to the reaction conditions and the efficiency and selectivity of the oxidations was accessed in a comparative study with MnTPP and MnEtio II. Copyright © 2001 John Wiley & Sons, Ltd. http://dx.doi.org/10.1002/jpp.332
The 2,3,7,8,12,13,17,18-octaphenylporphyrinato manganese(III) chloride was prepared and its behaviour as epoxidation catalyst was studied. The role of the phenyl substituents in the ß-pyrrolic positions concerning the stability of the catalyst to the reaction conditions and the efficiency and selectivity of the oxidations was accessed in a comparative study with MnTPP and MnEtio II. Copyright © 2001 John Wiley & Sons, Ltd. http://dx.doi.org/10.1002/jpp.332
Document Type
Article
Language English
Language English
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