Investigation of the garnet-perovskite transition in Nd doped YIG by means of m...

• Author(s): Hernández-Gómez, P. ; Francisco, C. de ; Torres, C. ; Iñiguez, J. ; Raposo, V. ; Perdigão, J. M. ; Ferreira, A. R.
• Date: 2004
• Persistent ID: http://hdl.handle.net/10316/8161
• Origin: Estudo Geral - Universidade de Coimbra
• Document Type: Article
• Language: English

Description

The garnet-perovskite transition is studied in this work with magnetic disaccommodation on polycrystalline Nd doped YIG samples Y3-xNdxFe5O12 (0 < x < 2.5). A very different behaviour with the sintering atmosphere is observed. The results of magnetic disaccommodation for samples sintered in air reveal that the low temperature peak of YIG at 120 K disappear and another peak emerge at 300 K with x = 2.0, when the solubility limit is surpassed and the compound contains secondary perovskite phase and magnetite. For CO2 sintered samples, the process at 120 K exhibit magnetic accommodation features (i.e. negative disaccommodation), and vanishes with increasing Nd substitution, together with the appearance of the 300 K peak associated with the garnet-perovskite transition which takes place with x ≈ 1.4 doping. Thermal evolution of magnetic permeability and X-ray diffraction support the behaviour observed. (© 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) http://dx.doi.org/10.1002/pssc.200304392