Autor(es):
Silveira, Dora M. 
; Caridade, Pedro J. S. B. ; Varandas, António J. C.
Data: 2004
Identificador Persistente: http://hdl.handle.net/10316/10405
Origem: Estudo Geral - Universidade de Coimbra
Detalhes do Documento
Dynamics Study of the O + HO2 Reaction Using Two DMBE Potential Energy Surfaces...
Descrição
We investigate the effect of vibrational excitation on the dynamics and kinetics of the atmospheric reaction O(3P) + HO2 → OH + O2 using two double many-body expansion potential energy surfaces previously reported. The results show that such an effect is relatively minor even considering HO2 with contents of vibrational excitation close to the H + O2 dissociation asymptote. It should therefore not bear drastic implications in atmospheric modeling where such an effect has been ignored thus far. http://dx.doi.org/10.1021/jp049575z
We investigate the effect of vibrational excitation on the dynamics and kinetics of the atmospheric reaction O(3P) + HO2 → OH + O2 using two double many-body expansion potential energy surfaces previously reported. The results show that such an effect is relatively minor even considering HO2 with contents of vibrational excitation close to the H + O2 dissociation asymptote. It should therefore not bear drastic implications in atmospheric modeling where such an effect has been ignored thus far. http://dx.doi.org/10.1021/jp049575z
Tipo de Documento
Artigo
Idioma Inglês
Idioma Inglês
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